Publication:
Effect of the Chemical and Phase Composition of Nanocrystalline Gadolinium Complex Oxides on the Propane Cracking Process

Дата
2020
Авторы
Markova, E. B.
Kovtun, S. O.
Tereshina, T. A.
Shchetinin, I. V.
Popov, V. V.
Menushenkov, A. P.
Yastrebtsev, A. A.
Molokova, A. Y.
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Организационные подразделения
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Институт лазерных и плазменных технологий
Стратегическая цель Института ЛаПлаз – стать ведущей научной школой и ядром развития инноваций по лазерным, плазменным, радиационным и ускорительным технологиям, с уникальными образовательными программами, востребованными на российском и мировом рынке образовательных услуг.
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Аннотация
© 2020, Pleiades Publishing, Ltd.Abstract: Effect of the chemical composition and crystal structure type of gadolinium complex oxides on their catalytic activity is studied. It is shown that nanocrystalline powders Gd2Ti2O7, Gd2Zr2O7, and Gd2Hf2O7 form highly symmetrical face-centered сubic crystal structures having localized (in Gd2Ti2O7) and delocalized (in Gd2Zr2O7 and Gd2Hf2O7) oxygen vacancies. At the same time, low-symmetrical crystal structures are formed in Gd2(WO4)3 (the monoclinic structure) and Gd2(МоO4)3 (a mixture of monoclinic and rhombic structures). Catalytic runs show that formation of the cubic structure contributes to an increase in the degree of conversion of propane and causes a shift in cracking temperatures to lower values. Formation of this type of nanocrystalline oxides facilitates the dehydrogenation reaction with propylene selectivity up to 80% at temperatures up to 700 К. Formation of the mixture of monoclinic and rhombic structures in Gd2(МоO4)3 leads to a shift in the degree of conversion to the catalytic temperature range of 700–900 К, in which the dehydrogenation reaction predominates (80%). In the case of the monoclinic structure of Gd2(WO4)3 in the same cracking temperature ranges the process of degradation occurs in parallel; this decreases propylene selectivity to 50% and promotes an increase in the yield of ethylene to 30%.
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Effect of the Chemical and Phase Composition of Nanocrystalline Gadolinium Complex Oxides on the Propane Cracking Process / Markova, E.B. [et al.] // Petroleum Chemistry. - 2020. - 60. - № 5. - P. 601-608. - 10.1134/S0965544120050060
URI
https://www.doi.org/10.1134/S0965544120050060
 https://www.scopus.com/record/display.uri?eid=2-s2.0-85085378908&origin=resultslist
 http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS_CPL&DestLinkType=FullRecord&UT=WOS:000534881800008
 https://openrepository.mephi.ru/handle/123456789/21856
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