Publication:
Magnetic Nanosorbents Based on Bentonite and CoFe2O4 Spinel

Дата
2022
Авторы
Khodosova, N.
Novikova, L.
Tomina, E.
Belchinskaya, L.
Tyupina, E. A.
Journal Title
Journal ISSN
Volume Title
Издатель
Научные группы
Организационные подразделения
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Организационная единица
Институт ядерной физики и технологий
Цель ИЯФиТ и стратегия развития - создание и развитие научно-образовательного центра мирового уровня в области ядерной физики и технологий, радиационного материаловедения, физики элементарных частиц, астрофизики и космофизики.
Выпуск журнала
Аннотация
New magnetic nanocomposite sorbents were obtained by doping natural bentonite with nanosized CoFe2O4 spinel (10 and 20 wt.%). Nanocrystals of cobalt ferrite were synthesized by a citrate burning method. The structure and physical-chemical properties of the composites were characterized by XRD, XRF, TEM, BET, FTIR and Faraday balance magnetometry. During the formation of nanocomposites, 10–30 nm particles of cobalt ferrite occupied mainly the interparticle space of Fe-aluminosilicate that significantly changed the particle morphology and composite porosity, but at the same time retained the structure of the 2:1 smectite layer. A combination of two functional properties of composites, adsorption and magnetism has been found. The adsorption capacity of magnetic nanosorbents exceeded this parameter for bentonite and spinel. Despite the decrease in the adsorption volume, pore size and specific surface area of the composite material relative to bentonite, the sorption activity of the composite increases by 12%, which indicated the influence of the magnetic component on the sorption process. FTIR data confirmed the mechanism of formaldehyde sorption by the composite sorbent. The production of a magnetic nanosorbent opens up new possibilities for controlling the sorption processes and makes it possible to selectively separate the sorbent from the adsorption medium by the action of a magnetic field.
Описание
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Цитирование
Magnetic Nanosorbents Based on Bentonite and CoFe2O4 Spinel / Khodosova, N. [et al.] // Minerals. - 2022. - 12. - № 11. - 10.3390/min12111474
URI
https://www.doi.org/10.3390/min12111474
 https://www.scopus.com/record/display.uri?eid=2-s2.0-85149532885&origin=resultslist
 http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS_CPL&DestLinkType=FullRecord&UT=WOS:000895580900001
 https://openrepository.mephi.ru/handle/123456789/28372
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