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Ion mobility spectrometry of N-methylimidazole and possibilities of its determination

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dc.contributor.authorAleksandrova, D. A.
dc.contributor.authorMelamed, T. B.
dc.contributor.authorBaberkina, E. P.
dc.contributor.authorFenin, A. A.
dc.contributor.authorShaltaeva, Y. R.
dc.contributor.authorBelyakov, V. V.
dc.contributor.authorШалтаева, Юлия Ринатовна
dc.contributor.authorБеляков, Владимир Васильевич
dc.date.accessioned2024-11-30T02:13:37Z
dc.date.available2024-11-30T02:13:37Z
dc.date.issued2021
dc.description.abstract© D.A. Aleksandrova, T.B. Melamed, E.P. Baberkina, A.A. Fenin, E.S. Osinova, A.E. Kovalenko, R.V. Yakushin, Yu.R. Shaltaeva, V.V. Belyakov, D.I. Zykova, 2021.Objectives. To determine the ion mobility of N-methylimidazole, establish the structure of ions corresponding to characteristic signals, and determine the detection limit of N-methylimidazole on the ion-drift detector Kerber. Methods. Ion mobility spectrometry was used to study the ionization processes. The enthalpies of the reactions of monomer and dimer ions were calculated in the ORCA 4.1.1 software by the B3LYP density functional method with a set of basic functions 6-31G (d, p). Results. The drift time and ion mobility values of N-methylimidazole were determined. A method for mathematical processing of spectra and a program for its implementation was developed. The changing peculiarities of the ion mobility spectrum during measurement at a given time were studied. According to the interpretation of the spectrum signals, the structure of the generated ions was proposed, and the enthalpies of ion formation were determined. Conclusions. The characteristic signal of the N-methylimidazole ion protonated at the nitrogen atom of the pyridine type was revealed. It was found that two signals in the ion mobility spectra of N-methylimidazole correspond to the presence of the monomer and dimer ions. The detection limit of N-methylimidazole on the ion-drift detector Kerber was determined, amounting to 3 pg.
dc.format.extentС. 512-525
dc.identifier.citationIon mobility spectrometry of N-methylimidazole and possibilities of its determination / Aleksandrova, D.A. [et al.] // Tonkie Khimicheskie Tekhnologii. - 2021. - 16. - № 6. - P. 512-525. - 10.32362/2410-6593-2021-16-6-512-525
dc.identifier.doi10.32362/2410-6593-2021-16-6-512-525
dc.identifier.urihttps://www.doi.org/10.32362/2410-6593-2021-16-6-512-525
dc.identifier.urihttps://www.scopus.com/record/display.uri?eid=2-s2.0-85124562846&origin=resultslist
dc.identifier.urihttps://openrepository.mephi.ru/handle/123456789/25255
dc.relation.ispartofTonkie Khimicheskie Tekhnologii
dc.titleIon mobility spectrometry of N-methylimidazole and possibilities of its determination
dc.typeArticle
dspace.entity.typePublication
oaire.citation.issue6
oaire.citation.volume16
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relation.isAuthorOfPublicatione931152d-aeb9-452a-bf37-27ce50e49743
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