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Frequency dispersion in the fractional Langmuir approximation for the adsorption-desorption phenomena

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dc.contributor.authorBarbero, G.
dc.contributor.authorEvangelista, L. R.
dc.contributor.authorLenzi, E. K.
dc.date.accessioned2024-11-26T14:22:13Z
dc.date.available2024-11-26T14:22:13Z
dc.date.issued2020
dc.description.abstractWe propose that a kinetic equation of fractional order may be used to account for the frequency dispersion of the effective parameters in the framework of the Langmuir approximation for the adsorption-desorption phenomena. A frequency dependence of these parameters naturally arises in this formalism, indicating that it may play a similar role of a generalization of the Langmuir isotherm obtained from a homogeneous distribution of relaxation times. The fractional approach formalism opens the possibility to consider different relaxation regimes characterizing the interfacial behaviour of electrolytic cells, and may be a powerful tool to interpret complex impedance spectroscopy data.
dc.identifier.citationFrequency dispersion in the fractional Langmuir approximation for the adsorption-desorption phenomena / Barbero, G, Evangelista, LR, Lenzi, EK // Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences. - 2020. - 476. - № 2238. - 10.1098/rspa.2019.0570
dc.identifier.doi10.1098/rspa.2019.0570
dc.identifier.urihttps://www.doi.org/10.1098/rspa.2019.0570
dc.identifier.urihttps://www.scopus.com/record/display.uri?eid=2-s2.0-85092376895&origin=resultslist
dc.identifier.urihttp://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS_CPL&DestLinkType=FullRecord&UT=WOS:000539300100002
dc.identifier.urihttps://openrepository.mephi.ru/handle/123456789/21944
dc.relation.ispartofProceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences
dc.titleFrequency dispersion in the fractional Langmuir approximation for the adsorption-desorption phenomena
dc.typeArticle
dspace.entity.typePublication
oaire.citation.issue2238
oaire.citation.volume476
relation.isOrgUnitOfPublicationc8407a6f-7272-450d-8d99-032352c76b55
relation.isOrgUnitOfPublication.latestForDiscoveryc8407a6f-7272-450d-8d99-032352c76b55
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