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Activator segregation and micro-luminescence properties in GAGG:Ce ceramics

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dc.contributor.authorDosovitskiy, G.
dc.contributor.authorDubov, V.
dc.contributor.authorKarpyuk, P.
dc.contributor.authorVolkov, P.
dc.contributor.authorPrikhodko, K.
dc.contributor.authorПриходько, Кирилл Евгеньевич
dc.date.accessioned2024-11-29T13:26:24Z
dc.date.available2024-11-29T13:26:24Z
dc.date.issued2021
dc.description.abstract© 2021ввCeramic scintillators are promising due to their potentially low cost. Here, we report on our study of Ce-doped ceramics. Typical garnet-type ceramics Gd2.97Ce0.03Al2Ga3O12 was fabricated for the study from co-precipitated powders by high-temperature sintering in air. Its structure and composition are characterized using Scanning Electron Microscope (SEM) imaging, Transmission Electron Microscopy (TEM), Electron Energy Loss Spectroscopy (EELS), Electron Backscattered Diffraction (EBSD) mapping, X-Ray Diffraction (XRD) and X-ray Absorption Near Edge Structure (XANES) measurements. The spatial distribution of luminescence properties at the micro-level is studied using scanning confocal microscopy. Cerium segregation at the grain boundaries was revealed by compositional characterization and is in line with enhanced Ce3+ photoluminescence observed at the boundaries. Meanwhile, no excess partitioning of Ce4+ ions at the grain boundaries is observed. It is found that most of Ce ions in the ceramics are stabilized in the state Ce3+, what is encouraging in view of the further development of GAGG:Ce ceramics as a promising luminescence material for lighting and scintillator application.
dc.identifier.citationActivator segregation and micro-luminescence properties in GAGG:Ce ceramics / Dosovitskiy, G. [et al.] // Journal of Luminescence. - 2021. - 236. - 10.1016/j.jlumin.2021.118140
dc.identifier.doi10.1016/j.jlumin.2021.118140
dc.identifier.urihttps://www.doi.org/10.1016/j.jlumin.2021.118140
dc.identifier.urihttps://www.scopus.com/record/display.uri?eid=2-s2.0-85104790131&origin=resultslist
dc.identifier.urihttp://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS_CPL&DestLinkType=FullRecord&UT=WOS:000663095300005
dc.identifier.urihttps://openrepository.mephi.ru/handle/123456789/23927
dc.relation.ispartofJournal of Luminescence
dc.titleActivator segregation and micro-luminescence properties in GAGG:Ce ceramics
dc.typeArticle
dspace.entity.typePublication
oaire.citation.volume236
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relation.isAuthorOfPublication.latestForDiscovery162432cf-0190-45b0-93f6-e38eae07a362
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