Publication: Synthesis of [99Tc(CO)6]+ Cation under Ambient Conditions
Дата
2022
Авторы
Sakhonenkova, A. P.
Slastihina, P. V.
Sidorenko, G. V.
Tyupina, M. Y.
Miroslavov, A. E.
Journal Title
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Аннотация
© 2022 Wiley-VCH GmbH.Technetium(I) and rhenium(I) hexacarbonyl cations were prepared for the first time at atmospheric pressure and room temperature by treatment of dichloromethane or chloroform solutions of [99TcBr(CO)5] and [ReCl(CO)5] with carbon monoxide in the presence of dry aluminum trichloride. The yield was 17.0 % and 3.1 %, respectively.
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Цитирование
Synthesis of [99Tc(CO)6]+ Cation under Ambient Conditions / Sakhonenkova, A.P. [et al.] // ChemistrySelect. - 2022. - 7. - № 15. - 10.1002/slct.202201128
URI
https://www.doi.org/10.1002/slct.202201128
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