Publication:
Kinetic Modeling of the Quenching of Combustion Products during the Synthesis of Acetylene

Дата
2019
Авторы
Troshin, K. Y.
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Научные группы
Организационные подразделения
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© 2019, Pleiades Publishing, Ltd.Abstract: The forced cooling of intermediate combustion products of rich oxygen mixtures of methane and its mixtures with propane was studied by computer simulation. The partial oxidation of the hydrocarbon feedstock was performed in the self-ignition mode at a constant pressure at temperatures of 773–973 K and pressures of 0.1–5.0 MPa. The disappearance of acetylene in the intermediate combustion products during the quenching was shown to be more active than when they equilibrated under adiabatic conditions. The forced cooling of the products can accelerate the disappearance of acetylene due to the different orders of the direct and reverse reactions of acetylene with active particles.
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Troshin, K. Y. Kinetic Modeling of the Quenching of Combustion Products during the Synthesis of Acetylene / Troshin, K.Y. // Russian Journal of Physical Chemistry B. - 2019. - 13. - № 4. - P. 577-584. - 10.1134/S1990793119040274
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