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pH-Sensing Platform Based on Light-Matter Coupling in Colloidal Complexes of Silver Nanoplates and J-Aggregates

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dc.contributor.authorRakovich, Y. P.
dc.contributor.authorKrivenkov, V.
dc.contributor.authorSamokhvalov, P.
dc.contributor.authorNabiev, I.
dc.contributor.authorСамохвалов, Павел Сергеевич
dc.contributor.authorНабиев, Игорь Руфаилович
dc.date.accessioned2024-11-29T11:31:53Z
dc.date.available2024-11-29T11:31:53Z
dc.date.issued2021
dc.description.abstract© 2021 American Chemical Society.Remote control of the pH of the medium is an important task for many applications in chemistry, medicine, and biology. Remote control of the pH using light is an intelligent and cost-effective approach. The nanoscale plasmon-exciton (plexciton) light-matter coupling is a physical phenomenon that provokes strong changes in the optical properties of the original plasmon and exciton bands, resulting in a transparency dip in the initial plasmon spectrum and formation of two hybrid plexciton side bands separated by the Rabi splitting energy. The plexciton coupling strength is unaffected by the temperature and light irradiation stressors but strongly depends on the transition dipole moment of the exciton material. Here, we show that the optical parameters of the plexciton coupling can be controlled by varying the pH of the medium. To demonstrate this, we obtained resonant light-matter coupling between the plasmon band of silver nanoplates and the J-band of J-aggregates with a Rabi splitting energy of up to 450 meV and found that both the extinction dip and the splitting energy are strongly affected by variation of pH from 2.5 to 11. We explain this effect by a change in the structure of the J-aggregates and reduction of the J-band intensity, which is confirmed by numerical simulation.
dc.identifier.citationpH-Sensing Platform Based on Light-Matter Coupling in Colloidal Complexes of Silver Nanoplates and J-Aggregates / Rakovich, Y.P. [et al.] // Journal of Physical Chemistry C. - 2021. - 10.1021/acs.jpcc.0c10602
dc.identifier.doi10.1021/acs.jpcc.0c10602
dc.identifier.urihttps://www.doi.org/10.1021/acs.jpcc.0c10602
dc.identifier.urihttps://www.scopus.com/record/display.uri?eid=2-s2.0-85100263289&origin=resultslist
dc.identifier.urihttp://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS_CPL&DestLinkType=FullRecord&UT=WOS:000614317500037
dc.identifier.urihttps://openrepository.mephi.ru/handle/123456789/23644
dc.relation.ispartofJournal of Physical Chemistry C
dc.titlepH-Sensing Platform Based on Light-Matter Coupling in Colloidal Complexes of Silver Nanoplates and J-Aggregates
dc.typeArticle
dspace.entity.typePublication
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