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Electric response of asymmetric electrolytic cells to small AC signals

dc.contributor.authorAlexe-Ionescu, A. L.
dc.contributor.authorEvangelista, L. R.
dc.contributor.authorBarbero, G.
dc.date.accessioned2024-11-26T14:35:07Z
dc.date.available2024-11-26T14:35:07Z
dc.date.issued2020
dc.description.abstract© 2020 Elsevier B.V.We present an extended theory for the electric response of an electrolytic cell with two different electrodes to a small amplitude external ac stimulus. In this case, the two electrodes limiting the cell are different in the sense that the spatial dependencies of the dynamical quantities characterising the system have not a well defined symmetry, with respect to the electrodes. This requires extending the Poisson-Nernst-Planck model to solve the fundamental equations allowing for the analytical determination of the electric impedance of the cell. The new theoretical framework opens the pathway to describe asymmetric electrolytic cells limited by conductive or adsorbing-desorbing boundaries.
dc.identifier.citationAlexe-Ionescu, A. L. Electric response of asymmetric electrolytic cells to small AC signals / Alexe-Ionescu, A.L., Evangelista, L.R., Barbero, G. // Journal of Electroanalytical Chemistry. - 2020. - 873. - 10.1016/j.jelechem.2020.114378
dc.identifier.doi10.1016/j.jelechem.2020.114378
dc.identifier.urihttps://www.doi.org/10.1016/j.jelechem.2020.114378
dc.identifier.urihttps://www.scopus.com/record/display.uri?eid=2-s2.0-85087327897&origin=resultslist
dc.identifier.urihttp://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS_CPL&DestLinkType=FullRecord&UT=WOS:000589178000003
dc.identifier.urihttps://openrepository.mephi.ru/handle/123456789/21982
dc.relation.ispartofJournal of Electroanalytical Chemistry
dc.titleElectric response of asymmetric electrolytic cells to small AC signals
dc.typeArticle
dspace.entity.typePublication
oaire.citation.volume873
relation.isOrgUnitOfPublicationc8407a6f-7272-450d-8d99-032352c76b55
relation.isOrgUnitOfPublication.latestForDiscoveryc8407a6f-7272-450d-8d99-032352c76b55
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