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Study of atmospheric pressure chemical ionization of phthalates in air by ion mobility spectrometry/mass spectrometry

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dc.contributor.authorMichalczuk, B.
dc.contributor.authorFateh, Borkhari, A.
dc.contributor.authorPapp, P.
dc.contributor.authorMoravsky, L.
dc.contributor.authorSysoev, A. A.
dc.contributor.authorMatejcik, S.
dc.contributor.authorСысоев, Алексей Александрович
dc.date.accessioned2024-11-29T18:10:35Z
dc.date.available2024-11-29T18:10:35Z
dc.date.issued2021
dc.description.abstract© 2021 John Wiley & Sons Ltd.Rationale: Phthalates are widely used in consumer products in the chemical industries. Due to their abundance in the milieu, their potentially harmful effect on the environment, human and animal health there is a need for sensitive and fast methods for their detection. Methods: Positive polarity Corona Discharge Atmospheric Pressure Chemical Ionization (CD-APCI) in the air was applied for ionization of phthalates. The ionization method for the phthalates was studied by atmospheric pressure Ion Mobility Spectrometry (IMS) and hybrid IMS/orthogonal acceleration Time-of-Flight Mass spectrometry (IMS-oaTOF-MS). Results: CD-APCI IMS and MS spectra of selected phthalates (dimethyl phthalate, diethyl phthalate, diethyl isophthalate, diethyl terephthalate, dipropyl phthalate, diisopropyl phthalate, dibutyl phthalate, diisobutyl phthalate, and dibutyl terephthalate) were recorded. In the case of the ortho- and “iso”-isomers exclusively the protonated molecular ions [M + H]+ were detected. In the case of the para- and meta-isomers and regioisomers, APCI resulted in the appearance of hydrated protonated molecular ions [M + H]+·(H2O)0,1,2. The ion mobilities, collision cross-sections of these ions in air, as well as the limits of detection (LODs) for the phthalate vapors, were determined. In the case of isomeric phthalates, we have demonstrated the potential of the IMS technique for their separation. Conclusions: The results show that CD-APCI in combination with IMS and IMS-oaTOF-MS is a suitable method for the fast and sensitive detection of phthalates with the potential to separate some isomers.
dc.identifier.citationStudy of atmospheric pressure chemical ionization of phthalates in air by ion mobility spectrometry/mass spectrometry / Michalczuk, B. [et al.] // Rapid Communications in Mass Spectrometry. - 2021. - 35. - № 17. - 10.1002/rcm.9145
dc.identifier.doi10.1002/rcm.9145
dc.identifier.urihttps://www.doi.org/10.1002/rcm.9145
dc.identifier.urihttps://www.scopus.com/record/display.uri?eid=2-s2.0-85112004403&origin=resultslist
dc.identifier.urihttp://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS_CPL&DestLinkType=FullRecord&UT=WOS:000681391200004
dc.identifier.urihttps://openrepository.mephi.ru/handle/123456789/24443
dc.relation.ispartofRapid Communications in Mass Spectrometry
dc.titleStudy of atmospheric pressure chemical ionization of phthalates in air by ion mobility spectrometry/mass spectrometry
dc.typeArticle
dspace.entity.typePublication
oaire.citation.issue17
oaire.citation.volume35
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