Publication:
Effect of Characteristics of Magnesium Oxide Powder on Composition and Strength of Magnesium Potassium Phosphate Compound for Solidifying Radioactive Waste

Дата
2019
Авторы
Vinokurov, S. E.
Kulikova, S. A.
Krupskaya, V. V.
Tyupina, E. A.
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Научные группы
Организационные подразделения
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Организационная единица
Институт ядерной физики и технологий
Цель ИЯФиТ и стратегия развития - создание и развитие научно-образовательного центра мирового уровня в области ядерной физики и технологий, радиационного материаловедения, физики элементарных частиц, астрофизики и космофизики.
Выпуск журнала
Аннотация
© 2019, Pleiades Publishing, Ltd.Phase composition, particle morphology, and granulometric composition of commercial samples of MgO powders of various chemical purities (classification from technical grade to chemical grade) prepared by heat treatment at 1300°C for 3 h were studied for the subsequent synthesis of a compound based on magnesium potassium phosphate matrix MgKPO4·6H2O, promising for solidifying liquid radioactive waste. It has been established that to obtain a homogeneous mineral-like compound with compressive strength of about 15 MPa, which meets the regulatory requirements for solidified forms of liquid radioactive waste, it is necessary to use magnesium oxide powder with a particle size of not more than 50 μm, which have a high degree of crystallinity (the average crystallite size is not less than 40 nm). It was noted that the impurities of metal compounds, primarily silicon, calcium, and iron in the MgO powder, do not affect the synthesis conditions and the mechanical strength of the compound.
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Цитирование
Effect of Characteristics of Magnesium Oxide Powder on Composition and Strength of Magnesium Potassium Phosphate Compound for Solidifying Radioactive Waste / Vinokurov, S.E. [et al.] // Russian Journal of Applied Chemistry. - 2019. - 92. - № 4. - P. 490-497. - 10.1134/S1070427219040049
URI
https://www.doi.org/10.1134/S1070427219040049
 https://www.scopus.com/record/display.uri?eid=2-s2.0-85066467419&origin=resultslist
 http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS_CPL&DestLinkType=FullRecord&UT=WOS:000470325100004
 https://openrepository.mephi.ru/handle/123456789/18177
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